Derive an expression for the rate constant of 2nd reaction of the type, 2A→product.

2A → Product
initial concentration : a molL-1                       →                              0
final concentration (t=t) : (a-x) molL-1             →                  x molL-1

Integrating,

Here, c is integration constant.

At,  t=0, x=0, then from equation (i), we have,

Hence,

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This is the required expression.

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Author: Tanmay Chakrabarty

A former CSE student, working as a SSE with 5+ years of experience in the field of Web Application development in PHP+MySQL platform with strong skills in JS, JQuery(+UI), HTML, CSS, Bootstrap.